Leaving US with Ukrainian non-biometrical passport, spending long layover in EU outside the airport?

My friend is Ukrainian. She is going to the US from Ukraine soon, and on the way back she has a 9-hour layover in Paris CDG.

Her US visa is in a non-biometrical passport, which doesn’t allow to enter EU without a visa. But she also has a biometrical one, which allows her to travel to EU (in Ukraine people can have up to 2 passports for travelling abroad).

How can she exit the airport during layover to take a walk in the city?

UPD: the question is more about the usage of passports, not the timing. Will she be able to use the biometrical one to leave the airport, if the boarding pass will be for the non-biometrical one?

visas eu

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Leaving US with Ukrainian non-biometrical passport, spending long layover in EU outside the airport? - Flags waving on old ornate city building on fine day

Leaving US with Ukrainian non-biometrical passport, spending long layover in EU outside the airport? - Long exposure of famous suspension Golden Gate Bridge with glowing lights crossing calm river in dusky time with fog in San Francisco

Leaving US with Ukrainian non-biometrical passport, spending long layover in EU outside the airport? - Photo Of Skate Park During Daytime

Can Ukrainians leave Ukraine without passport?

Travel documents of Ukrainian citizens For traveling to certain countries, Ukrainians do not need to use a passport, as they may use their Ukrainian identity card.

Can I enter Europe with Ukrainian passport?

If you have Ukrainian nationality and a biometric passport, you can enter the EU by presenting your passport at the border.

Do Ukrainians need visa to travel in Europe?

Will Ukrainian citizens need a visa for Europe? No, Ukrainians will not need a visa to travel to the Schengen Area for up to 90 days. Ukrainians will maintain their visa-free privileges when visiting other European destinations for tourism, business or transit.

Is Ukraine in the Schengen zone?

That allows them to enter any country that is a part of the Schengen Area Treaty. Unfortunately, Ukraine is not a part of that treaty, and while there are a few countries in the world that accept a Schengen visa, Ukraine is not one of them.

Deported from Ukraine Europe Visa Process - Kiev Borispol Airport

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Images: William Fortunato, ArtHouse Studio, Simon Shim, Ana Arantes